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TAP TIMES          -33-                                    OCTOBER 2022



           Biodegradable PC board (from 32)                     for seven months. After pulling the cir-
                                                                cuit from storage, the researchers applied
        the end of a polymer chain. By control-                 continuous electrical voltage to the device
        ling when the lipase finds the chain end,               for a month and found that the circuit
        it is possible to ensure the materials don’t            conducted electricity just as well as it did
        degrade until the water reaches a certain               before storage.
        temperature.
                                                                Immersed in warm water
        Shelf-ready BC lipase “cocktails”                       Next, the researchers put the device’s re-
        For the current study, Xu and her team                  cyclability to test by immersing it in warm
        simplified the process even further. In-                water.
        stead of expensive purified enzymes, the
        biodegradable printed circuits rely on                  Within 72 hours, the circuit materials de-
        cheaper, shelf-ready BC lipase “cocktails.”             graded into its constituent parts — The
                                                                silver particles completely separated from
                                                                the polymer binders, and the polymers
        This significantly reduces costs, facilitating          broke down into reusable monomers, al-
        the printed circuit’s entry into mass manu-             lowing the researchers to easily recover
        facturing, Xu said.                                     the metals without additional processing.

        By doing so, the researchers advanced                   By the end of this experiment, they de-
        the technology, enabling them to develop                termined that approximately 94% of the
        a printable “conductive ink” composed of                silver particles can be recycled and reused
        biodegradable polyester binders, conduc-                with similar device performance.
        tive fillers such as silver flakes or carbon
        black, and commercially available enzyme                That the circuit’s degradability continued
        cocktails.                                              after 30 days of operation surprised the
                                                                researchers, suggesting that the enzymes
        Electrically conducive ink                              were still active.
        The ink gets its electrical conductivity from
        the silver or carbon black particles, and               “We were surprised”
        the biodegradable polyester binders act as              “We were surprised that the enzymes
        a glue.                                                 ‘lived’ for so long. Enzymes aren’t de-
                                                                signed to work in an electric field,” Xu

        The researchers supplied a commercial 3D                said.
        printer with the conductive ink to print cir-
        cuit patterns onto various surfaces such as             Xu attributes the working enzymes’ lon-
        hard biodegradable plastic, flexible biode-             gevity to the biodegradable plastic’s mo-
        gradable plastic, and cloth.                            lecular structure.

                                                                In their previous study, the researchers
        This proved that the ink adheres to a vari-             learned that adding an enzyme protec-
        ety of materials, and forms an integrated               tant called random heteropolymer, or RHP,
        device once the ink dries. To test its shelf            helps to disperse the enzymes within the
        life and durability, the researchers stored a           mixture in clusters a few nanometers (bil-
        printed circuit in a laboratory drawer with-            lionths of a meter) in size.
        out controlled humidity or temperature                                                         next page
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