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TAP TIMES          -20-                                   AUGUST 2022


                Perovskites could take
             solar panels to new heights


        CAMBRIDGE, Mass. — Perovskites hold
        promise for creating solar panels that
        could be easily deposited onto most
        surfaces, including flexible and tex-
        tured ones.


        Lightweight and efficient
        These materials would also be lightweight,              Are  perovskites  a  replacement  for  silicon? Some  researchers
        cheap to produce, and as efficient as to-               think so. (Pixabay)
        day’s leading photovoltaic materials, which             covered in 1839 and named after Russian
        are mainly silicon.                                     mineralogist L.A. Perovski.


        They’re the subject of increasing research              Distinctive crystal configuration
        and investment, but companies looking to                The original mineral perovskite, which is
        harness their potential do have to address              calcium titanium oxide (CaTiO3), has a
        some remaining hurdles before perovskite-               distinctive crystal configuration. It has a
        based solar cells can be commercially                   three-part structure, whose components
        competitive.                                            have come to be labeled A, B and X, in

                                                                which lattices of the different components
        The term perovskite refers not to a specific            are interlaced.
        material, like silicon or cadmium telluride,
        other leading contenders in the photovol-               The family of perovskites consists of the
        taic realm, but to a whole family of com-               many possible combinations of elements
        pounds.                                                 or molecules that can occupy each of the
                                                                three components and form a structure
        The perovskite family of solar materials                similar to that of the original perovskite
        is named for its structural similarity to a             itself.
        mineral called perovskite, which was dis-
                                                                Bending the rules
                                                                (Some researchers even bend the rules a
                                                                little by naming other crystal structures
                                                                with similar elements “perovskites,” al-
                                                                though this is frowned upon by crystallog-
                                                                raphers.)

                                                                “You can mix and match atoms and mol-
                                                                ecules into the structure, with some limits.
                                                                For instance, if you try to stuff a molecule
                                                                that’s too big into the structure, you’ll dis-
                                                                tort it.


        Perovskites are seen as the next likely platform for solar cells,    “Eventually you might cause the 3D crystal
        replacing silicon. (Olivares/DAniloff, MIT)-                                                   next page
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